Upper Ocean Temperatures Hit Record High in 2020

The long-term warming of the ocean is a critical indicator of both the past and present state of the climate system. It also provides insights about the changes to come, owing to the persistence of both decadal variations and secular trends,which the ocean records extremely well(Hansen et al., 2011;IPCC, 2013;Rhein et al., 2013;Trenberth et al., 2016;Abram et al., 2019).     

Isotopic-geochemical evidence for crustal contamination of eclogites in the Kokchetav subduction-collision zone

This paper reports isotopic and geochemical studies of eclogites from the western ultrahigh pressure (UHP) and eastern high-pressure (HP) blocks of the Kokchetav subduction-collision zone. These HP and UHP eclogites exhumed in two stages: (1) The rocks of the western block metamorphosed within the field of diamond stability (e.g., Kumdy-Kol and Barchy); (2) In contrast, the metamorphic evolution of the eastern block reached the pressure peak within the stability field of coesite (e.g., Kulet, Chaglinka, Sulu-Tyube, Daulet, and Borovoe). The eclogites vary widely in the ratios of incompatible elements and in the isotope ratios of Nd (¹⁴³Nd/¹⁴⁴Nd = 0.51137-0.513180) and Sr (⁸⁷Sr/⁸⁶Sr = 0.703930.78447). The Sulu-Tyube eclogites display isotope-geochemical features close to N-MORB, while those from the other sites are compositionally similar to E-type MORB or island arc basalts (IAB). The model ages T_Nd(DM) of eclogites vary between 1.95 and 0.67 Ga. The Sulu-Tyube eclogite yields the youngest age; it has the values of ε_Nd(T) (7.2) and ⁸⁷Sr/⁸⁶Sr (0.70393) close to the depleted mantle values. The crustal input to the protolith of the Kokchetav eclogites is evident on the ε_Nd(T)-⁸⁶Sr/⁸⁷Sr and ε_Nd(T)-T plots. The eclogites make up a trend from DM to country rocks. Some eclogites from the Kulet, Kumdy-Kol, and Barchy localities display signs of partial melting, such as high Sm/Nd (0.65-0.51) and low (La/Sm)_N (0.34-0.58) values. The equilibrium temperatures of these eclogites are higher than 850 °C. The geochemical features of eclogites testify to the possibility of the eclogite protolith formation in the tectonic setting of passive continental rift margin subducted to depths over 120 km.     

Authigenic rhodochrosite from a gas hydrate-bearing structure in Lake Baikal

International Journal of Earth Sciences - Early diagenetic carbonates are rare in Lake Baikal. Siderite (Fe carbonate) concretions in the sediments were discovered only recently. Here, we discuss...     

The role of aerosols and greenhouse gases in Sahel drought and recovery

Climatic Change - We exploit the multi-model ensemble produced by phase 5 of the Coupled Model Intercomparison Project (CMIP5) to synthesize current understanding of external forcing of Sahel...     

Holocene hydrological variability of Lake Ladoga,northwest Russia,as inferred from diatom oxygen isotopes

This article presents a new comprehensive assessment of the Holocene hydrological variability of Lake Ladoga, northwest Russia. The reconstruction is based on oxygen isotopes of lacustrine diatom silica (δ¹⁸O_diatom) preserved in sediment core Co 1309, and is complemented by a diatom assemblage analysis and a survey of modern isotope hydrology. The data indicate that Lake Ladoga has existed as a freshwater reservoir since at least 10.8 cal. ka BP. The δ¹⁸O_diatom values range from +29.8 to +35.0‰, and relatively higher δ¹⁸O_diatom values around +34.7‰ between c. 7.1 and 5.7 cal. ka BP are considered to reflect the Holocene Thermal Maximum. A continuous depletion in δ¹⁸O_diatom since c. 6.1 cal. ka BP accelerates after c. 4 cal. ka BP, indicating Middle to Late Holocene cooling that culminates during the interval 0.8–0.2 cal. ka BP, corresponding to the Little Ice Age. Lake‐level rises result in lower δ¹⁸O_diatom values, whereas lower lake levels cause higher δ¹⁸O_diatom values. The diatom isotope record gives an indication for a rather early opening of the Neva River outflow at c. 4.4–4.0 cal. ka BP. Generally, overall high δ¹⁸O_diatom values around +33.5‰ characterize a persistent evaporative lake system throughout the Holocene. As the Lake Ladoga δ¹⁸O_diatom record is roughly in line with the 60°N summer insolation, a linkage to broader‐scale climate change is likely.     

Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.     

Thermal anomalies associated with shallow gas hydrates in the K-2 mud volcano, Lake Baikal

Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m^–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.     

Stability of phlogopite in ultrapotassic kimberlite-like systems at 5.5–7.5 GPa

Hydrous K-rich kimberlite-like systems are studied experimentally at 5.5–7.5 GPa and 1200–1450?°C in terms of phase relations and conditions for formation and stability of phlogopite. The starting samples are phlogopite–carbonatite–phlogopite sandwiches and harzburgite–carbonatite mixtures consisting of Ol?+?Grt?+?Cpx?+?L (±Opx), according to the previous experimental results obtained at the same P–T parameters but in water-free systems. Carbonatite is represented by a K- and Ca-rich composition that may form at the top of a slab. In the presence of carbonatitic melt, phlogopite can partly melt in a peritectic reaction at 5.5 GPa and 1200–1350?°C, as well as at 6.3–7.0 GPa and 1200?°C: 2Phl?+?CaCO₃ (L)?Cpx?+?Ol?+?Grt?+?K₂CO₃ (L)?+?2H₂O (L). Synthesis of phlogopite at 5.5 GPa and 1200–1350?°C, with an initial mixture of H₂O-bearing harzburgite and carbonatite, demonstrates experimentally that equilibrium in this reaction can be shifted from right to left. Therefore, phlogopite can equilibrate with ultrapotassic carbonate–silicate melts in a?≥?150?°C region between 1200 and 1350?°C at 5.5 GPa. On the other hand, it can exist but cannot nucleate spontaneously and crystallize in the presence of such melts in quite a large pressure range in experiments at 6.3–7.0 GPa and 1200?°C. Thus, phlogopite can result from metasomatism of peridotite at the base of continental lithospheric mantle (CLM) by ultrapotassic carbonatite agents at depths shallower than 180–195 km, which creates a mechanism of water retaining in CLM. Kimberlite formation can begin at 5.5 GPa and 1350?°C in a phlogopite-bearing peridotite source generating a hydrous carbonate–silicate melt with 10–15 wt% SiO₂, Ca# from 45 to 60, and high K enrichment. Upon further heating to 1450?°C due to the effect of a mantle plume at the CLM base, phlogopite disappears and a kimberlite-like melt forms with SiO₂ to 20 wt% and Ca#?=?35–40.     

Kinematical characteristics of the factorized velocity model

The factorized velocity model that incorporates both vertical heterogeneity and constant anisotropy is one of the complicated analytical models used in seismic data processing and interpretation. In this paper, I derive the analytic equations for offset, traveltime and relative geometrical spreading for the quasi‐compressional (qP‐) waves that can be used for modelling and inversion of the traveltime parameters. I show that the presence of anelliptic anisotropy usually dominates over the vertical heterogeneity with respect to the non‐hyperbolicity of the factorized velocity model.